• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A METHOD FOR MAKING A KATUNE-EXCHANGE MEMBRANE to obtain adiponitrile by electrochemical reduction of acrylonitrile, including the manufacture of fiberglass yarn. folding it, making a fabric from yarn, applying an ion exchange material to the fabric, characterized in that, in order to reduce the membrane's flowability during its operation, the yarn is additionally subjected to high-volume texturing processing until an infrared absorption ratio of 1000 cm for the fabric yarn to infrared absorption of untreated tissue, equal to 1.2-5.0, and until the ratio of specific conductivity is reached at a frequency of 1000 Hz i in 0.5 n. an aqueous solution of sodium chloride at 25 ° C for a fabric of treated yarn to an electrical conductivity of the fabric of raw yarn of 1.05-1.25.
    公开号:SU1116979A3
    申请号:SU802959597
    申请日:1980-08-08
    公开日:1984-09-30
    发明作者:Ватанабе Итару；Ватая Изаму；Цусима Сакае
    申请人:Асахи Касеи Когио Кабусики Кайся (Фирма)；
    IPC主号:
    专利说明:

    9) UDD The invention relates to electrochemical production, in particular to the manufacture of membranes for the preparation of adiponitrile. A known method of manufacturing a cation exchange membrane for the production of adiponitrile by electrochemical reduction of acrylonitrile involves the manufacture of fiberglass yarn, folding it, the fabric production of yarn, the deposition of ion-exchange material on the fabric. A disadvantage of the known method is that during the operation of the membranes during the electrochemical preparation of adiponitrile, the membrane flowability increases, which leads to disruption of the process and a decrease in its network efficiency l. The goal of the invention is to reduce the membrane flow during its operation. The goal is achieved by the fact / according to the method of manufacturing a cation-exchange membrane for obtaining adiponitrile electrochemical F1 by reducing acrylonitrile, including making yarn from fiberglass, folding it, making fabric from yarn, the application of an ion-exchange material to the fabric, the yarn is additionally subjected to high-volume texturing processing to reach the ratio of infrared absorption at a wavenumber of 1000 cm for Kani from the treated yarns by infrared absorption mk or untreated yarn equal to 1.2-5.0, and the ratio to dostshkeni conductivity Tote hour at 1,000 Hz 0.5N. an aqueous solution of sodium chloride at 25 ° C for a fabric of treated yarn to an electrical conductivity of the fabric of untreated yarn 1.05-1.25. Example. 200 filaments of alkaline glass fiber having a diameter of 9 microns are bonded to the 1st knot, which is then subjected to primary twisting. Four bundles of fibers are folded from to form the primary intermediate folded pr1-1-1. Then, two pieces of the first intermediate folded yarn are folded to form a second intermediate yarn. After that, the pieces of the second intermediate folded yarn are folded once more, and a folded yarn is obtained, which is subjected to a high volume texturing treatment. The treatment is carried out with an air jet at a pressure of 7 kg / cm at a processing speed of 150 m / min. Fabrics of plain weave are made from this yarn at a density of a basis - A yarn per inch of length and weft - 8 yarns per inch of the width of the dressing. The fabric is treated with a vinyl silane binder. The specific electrical conductivity of the fabric is determined by placing it in a cell between two electrodes through which an alternating current of 1000 Hz frequency is passed. Measurements are carried out in 0.5 n. an aqueous solution of sodium chloride at 25 ° C, for both treated and untreated fabric. The high volume texturing yarn processing is carried out in such a way that the ratio of the specific electrical conductivity for the fabric of the treated yarn to the electric conductivity of the fabric of the raw yarn (Cd) is. 1.19, and the ratio of infrared absorption at a wave number of 1000 cm for a fabric of treated yarn to infrared absorption of a fabric of raw yarn (K /,) is 2.4. The fabric is immersed in a mixture solution of styrene, divincyl benzene (purity approximately 55 wt.%), Dioctiphthalate and benzoyl peroxide (at a weight ratio of 75: 25: 90: 0.2) and polymerization is carried out by gradually heating the solution from room temperature to 100 ° C. The membrane with the tissue embedded in it is subjected to sulfonation in a 5% solution of the adduct of sulfuric anhydride and dioxane in dichloroethane. The thickness of the membrane is 1, 65 mm. The cation-exchange membrane is washed with an aqueous solution of sodium chloride and then with water. The water permeability of the cation-exchange membrane, which is 10 ml / m in 1 hour, is measured. The cation-exchange membrane is used to obtain adiponitrile by acrylonitrile recovery at a current density of 20 A / dm, 50 C 3500 hours and the water permeability is measured, which is 15 mp / m per hour, which meets the requirements of the process. The membrane is made by a known method under the same conditions, but without a high-volume texture. 311169794 mey processing to a certain value- operation. Experiments with an estimated K / (and K, j. The permeability is that if the additional textuion-exchange membrane constitutes the processing treatment is carried out to a value of 100 ml / m 1 h and continues with its K from 1.2 to 5.0, and K from 1.05 operation under the same conditions to 5 to 1.25, the effect of a decrease of 1000 ml / m per hour after 500 hours of membrane leakage compared with the invention is achieved. The invention reduces the decrease in leakage and leakage of the flow rate. there are no membranes for comparison with the prototype, and the value of the diponitrile in the electrochemical field is 10 x, 0 and 25 tc formation of acrylonitrile with its voltage drop across the membranes with the prototype. At the values of, 2
    权利要求:
    Claims (1)
    [1]
    METHOD FOR PRODUCING A CATION-EXCHANGE MEMBRANE for the production of adiponitrile by electrochemical reduction of acrylonitrile, including the manufacture of fiberglass yarn, folding it, fabricating yarn, applying ion-exchange material to the fabric, characterized in that, in order to reduce the membrane permeability during its operation, yarn is additionally subjected to texturing treatment to achieve a ratio of infrared absorption at a wavenumber of 1000 cm '1 for tissue from the treated yarn to infrared mu absorbance of untreated fabric The direct! Ms equal to 1.2-5.0, and to achieve a ratio of conductivity at a frequency of 1,000 Hz 0.5N. an aqueous solution of sodium chloride at 25 ° C for the fabric from the processed yarn to the electrical conductivity of the fabric from the untreated yarn, equal to 1.05-1.25.
    SU, t 1116979
    11 16979
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    同族专利:
    公开号 | 公开日
    GB2057012B|1983-03-02|
    FR2462936A1|1981-02-20|
    GB2057012A|1981-03-25|
    IT8024096D0|1980-08-08|
    DE3029870C2|1983-12-08|
    DE3029870A1|1981-02-26|
    IT1132381B|1986-07-02|
    FR2462936B1|1983-09-23|
    JPS6216965B2|1987-04-15|
    BR8004963A|1981-05-12|
    JPS5626554A|1981-03-14|
    US4337141A|1982-06-29|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US3120463A|1964-02-04|Porous fibrous sheet material |
    US3356607A|1964-07-22|1967-12-05|Ionics|Reinforced ion-exchange membranes|
    US3607706A|1967-08-04|1971-09-21|Ionics|Method of making stable laminated cation-exchange membranes|
    US3616319A|1968-02-09|1971-10-26|Monsanto Co|Electrolytic hydrodimerization of olefinic compounds|
    BE871096A|1978-10-09|1979-04-09|Diamond Shamrock Corp|PROCESS FOR TREATING THE REVERSE OF A MEMBRANE REINFORCED BY A FABRIC.|NO148267C|1981-06-16|1983-09-07|Norsk Hydro As|Water electrolysis diaphragm|
    US4999098A|1984-10-04|1991-03-12|Dionex Corporation|Modified membrane suppressor and method for use|
    EP1712660A1|2005-04-12|2006-10-18|Enthone Inc.|Insoluble anode|
    EP1717351A1|2005-04-27|2006-11-02|Enthone Inc.|Galvanic bath|
    RU2519455C2|2009-10-26|2014-06-10|Асахи Касеи Кемикалз Корпорейшн|Cation-exchange membrane, electrolyser applying thereof and method of manufacturing thereof|
    US10775339B2|2014-11-26|2020-09-15|Gentex Corporation|Membranes for use in electrochemical sensors and associated devices|
    CN107208286B|2015-01-21|2019-03-01|株式会社东芝|Porous diaphragm, its manufacturing method, hypochloric acid water manufacture electrode unit and the hypochloric acid water manufacturing device for having used it|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    JP54101180A|JPS6216965B2|1979-08-10|1979-08-10|
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